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Neutralizing Fluorocarbons

Posted by keelynet on September 7, 2008

Another weapon against global warming.

“A new catalyst breaks down greenhouse gases and pollutants at room temperature. One type of fluorocarbon, the ozone-destroying chlorofluorocarbons (CFCs), has now been widely banned under the Montreal Protocol, but the two other main types also present environmental problems. One of them is now used instead of CFCs as a coolant in refrigerators and air-conditioning units. Where such refrigerants leak into the environment, they function as greenhouse gases that are a thousand times more potent than carbon dioxide. Another type of fluorocarbon is used in many medical applications, including artificial blood. It, too, is a potent greenhouse gas and gets into the atmosphere as a by-product of the aluminum industry. But some species of it are also toxic and accumulate in the food chain, possibly increasing risk of cancer, birth defects, and other health problems. Brandeis’s Oleg Ozerov, lead researcher of the current Science study, found a way to crack the carbon-fluorine bond by using a silicon-based catalyst that recycles itself, so it can spark the breakdown reaction over and over again. “The basic idea is that we use three things: the fluorocarbon, a silicon-based hydrogen source, and a catalyst which mediates between the two to replace the fluorine in the fluorocarbon with hydrogen,” says Ozerov. “The active part of the catalyst is a positively charged silicon compound that kicks off the reaction by ripping the fluorine out of the fluorocarbon bond.” Having a fluorine ripped out, explains Ozerov, causes the former fluorocarbon to pull a hydrogen molecule out of the silicon-based material. Losing a hydrogen, in turn, transforms the silicon-based material into another instance of the catalyst, so the reaction can continue.” – Source

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